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第五娟 教授

日期:2015-10-06 人气:1788 


第五娟,高聘教授、硕士生导师

电话:0512-65882579    

传真:0512-65884380

电子邮箱:diwujuan@suda.edu.cn

通讯地址:苏州工业园区仁爱路199号, 邮编215123


个人简历:

第五娟  苏州大学医学部欧洲杯官网、放射医学及交叉学科研究院高聘教授,硕生生导师。2008年毕业于中国科学技术大学材料科学与工程系材料化学专业。2012年8月毕业于美国圣母大学锕系元素能源前沿研究中心,获博士学位,导师Prof. Thomas E. Albrecht-Schmitt。 2012年8月起在加州大学伯克利分校化学系及劳伦斯伯克利国家实验室开展博士后研究工作,合作导师 美国科学院院士Prof. Kenneth N. Raymond和Dr. David K. Shuh。

主要研究方向集中在锕系元素配位化学,并将其应用于核乏废料后处理,环境中核素迁移机制研究和体内放射性核素促排药物的研究中,具体工作内容涵盖了放射化学、核科学与技术及环境化学等多个交叉研究领域。迄今为止共发表SCI论文28篇(其中一作9篇),所有发表文章的总引用320余次,其中他引280次,H因子11。受邀为英国皇家化学会RSC出版的《Metal Phosphonate Chemistry》一书撰写第19章 “Structural Chemistry of Transuranium  Phosphonates”,综述了超铀元素有机磷酸盐体系的结构特点。


科研项目:

⒈ 国家自然科学基金委员会面上项目,溶剂热和离子热法制备锕系元素有机膦酸盐晶体及其光谱表征(21471107),2014年 ,85万, 主持

⒉ 国家自然科学基金委员会青年基金 羟基吡啶酮类药物对锕系元素的广谱促排机理和效果研究,(81402628),2014年, 23万,主持

⒊ 江苏省自然科学基金青年基金,2014年,离子液体中有机磷类配体对锕系元素萃取机理的配位化学研究(BK20140303),20万,主持

⒋ 江苏省“博士计划”世界名校类, 2014年,15万,主持

代表性论著:

1.期刊论文:

(1) J. Diwu, D. J. Grant, S. Wang, L. Gagliardi, T. E. Albrecht-Schmitt, “Periodic Trends in Lanthanide and Actinide Phosphonates: Discontinuity between Plutonium and Americium” Inorg. Chem., 51, 6906-6915, 2012;

(2) J. Diwu, Thomas E. Albrecht-Schmitt*, “Mixed-Valence Uranium (IV, VI) Diphosphonates: Synthesis, Structure and Spectroscopy” Inorg. Chem., 51, 4432-4434, 2012;

(3)J. Diwu, Thomas E. Albrecht-Schmitt*, “Chiral Uranium Methylenediphosphonate Framework Structure with High Porosity that is Built from Achiral Units” Chem. Comm., 48, 3827-2829, 2012;

(4) J. Diwu, S. Wang, T. E. Albrecht-Schmitt, “Periodic Trends in Hexanuclear Clusters” Inorg. Chem., 51, 4088-4093, 2012;

(5) J. Diwu, S. Wang, J. Good, D. Victoria, T. E. Albrecht-Schmitt, “Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates” Inorg. Chem., 50, 4842-4850, 2011;

(6) J. Diwu, J. J. Good; V. H. Di Stefano; T. E. Albrecht-Schmitt, “Self-Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity” Eur. J. Inorg. Chem., 9, 1374-1377, 2011;

(7) J. Diwu, S. Wang, Z. Liao, P. C. Burns, T. E. Albrecht-Schmitt, “Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates” Inorg. Chem., 49, 10074-10080, 2010;

(8) J. Diwu, A. Nelson, S. Wang, T. E. Albrecht-Schmitt, “Comparisons of Pu(IV) and Ce(IV) Diphosphonates” Inorg. Chem., 49, 3337-3342, 2010;

(9) J. Diwu, A-G. D. Nelson, T. E. Albrecht-Schmitt*, “Using Phosphonates to Probe Structural Differences between Transuranium Elements and their Proposed Surrogates” Comments on Inorganic Chemistry., 31(1 & 2), 46-62, 2010;

(10) J. Lin, J. N. Cross, J. Diwu, M. J. Polinski, N. A. Meredith, T. E. Albrecht-Schmitt, “Comparisons of Plutonium(IV), Thorium(IV), and Cerium(III) Tellurite Sulfates” ” Inorg. Chem., 52(8), 4277-4281, 2013;

(11) S. Wang, T. G. Parker, D. J. Grant, J. Diwu, E. V. Alekseev, E. Depmeier, L. Gagliardi, T. E. Albrecht-Schmitt, “Elucidation of Tetraboric Acid with a New Borate Fundamental Building Block in a Chiral Uranyl Fluoroborate” Inorg. Chem., 51, 11211-11213, 2012;

(12) J. Lin, J. N. Cross, J. Diwu, M. J. Polinski, E. M. Villa, T. E. Albrecht-Schmitt, “Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)” Inorg. Chem., 51, 11949-11954, 2012;

(13) J. Lin, J. Diwu, J. N. Cross, E. Villa, T. E. Albrecht-Schmitt, “Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl- or Br-): The First Cerium-Containing Cationic Frameworks” Inorg. Chem., 51, 10083-10085, 2012;

(14) J. N. Cross, E. M. Villa, S. Wang, J. Diwu, M. J. Polinski, T. E. Albrecht-Schmitt, “Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III)” Inorg. Chem., 51, 8419-8424, 2012;

(15) S. Wang, J. Diwu, E. V. Alekseev, L. Jouffret, W. Depmeier, T. E. Albrecht-Schmitt, “Cation-Cation Interactions Between Neptunyl(VI) Units” Inorg. Chem., 51, 7016-7018, 2012;

(16) S. Wang, P. Yu, B. A. Purse, M. J. orta, J. Diwu, W. H. Casey, B. L. Phillips, E. V. Alekseev, W. Depmeier, D. T. Hobbs, T. E. Albrecht-Schmitt, “Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4? in a Supertetrahedral Cationic Framework” Adv. Funct. Mater., 22, 2241–2250, 2012;

(17) S. Wu, S. Wang, J. Diwu, W. Depmeier, T. Malcherek, E. V. Alekseev,  T. E. Albrecht-Schmitt, “Complex Clover Cross-Sectioned Nanotubules Exist in the Structure of First Uranium Borate Phosphate” Chem. Commun., 48, 3479-3481, 2012;

(18) S. Wang, J. Diwu, A. Simonetti, C. H. Booth, T. E. Albrecht-Schmitt, “Interstitial Incorporation of Plutonium into a Low Dimensional Potassium Borate” Environ. Sci. Technol., 45, 9457-9463, 2011;

(19) S. Wang, E. V. Alekseev, J. Diwu, H. M. Miller, A. Oliver, G. Liu, W. Depmeier, T. E. Albrecht-Schmitt, “Functionalization of Borate Networks by the Incorporation of Fluoride: Syntheses, Crystal Structures, and Nonlinear Optical Properties of Novel Actinide Fluoroborates” Chem. Mater., 23, 2931-2939, 2011;

(20) S. Wang, E. M. Villa, J. Diwu, E. V. Alekseev, W. Depmeier, T. E. Albrecht-Schmitt, “Role of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates” Inorg. Chem., 50, 2527-2533, 2011;

(21) S. Wang, E. V. Alekseev, J. Diwu, W. Casey, B. Phillips, W. Depmeier, T. E. Albrecht-Schmitt, “NDTB-1: A Supertetrahedral Cationic Framework that Removes TcO4- from Solution” Angew. Chem. Int. Ed., 49, 1057-1060, 2010;

⒉ 专著:

J. Diwu and T. E. Albrecht-Schmitt, in Metal Phosphonate Chemistry, chapter 19, Chemistry of Transuranium Phosphonates (Eds: Abraham Clearfield, and Konstantinos Demadis), RSC Publishing, London, 607-631, 2011.

荣誉奖励:

⒈ 2014年 江苏省科协优秀青年科学工作者

⒉ 2014年“江苏省双创博士计划”

⒊ 2011年 圣母大学 环境放射化学领域Bayer fellowship

课程教学及招生信息:

⒈ 放射化学(研究生、本科生课程),参与

⒉ “苏大课程2014—3I工程”全英文教学示范课程, 放射化学,主持

长期招收无机化学,环境化学及放射医学的优秀研究生及科研助理。同时欢迎化学专业及医学类本科生提前来我们课题组参加带薪科研和完成毕业论文。


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