恭喜王艳龙老师关于手性锕系MOF的文章发表在Dalton上！
Yanlong Wang, Yuxiang Li, Zhuanling Bai, Chengliang Xiao, Zhiyong Liu, Wei Liu, Lanhua Chen, Weiwei He, Juan Diwu, Zhifang Chai, Thomas Albrecht-Schmitt and Shuao Wang*, Design and Synthesis of a Chiral Uranium-based Microporous Metal organic Framework with High SHG Efficiency and Sequestration Potential for Low-Valent Actinides, Dalton Trans., 2015, Accepted.
Abstract: The solvothermal reaction of tris-(4-carboxylphenyl)phosphineoxide] (H3TPO) with UO2(NO3)2•6H2O in DMF affords a uranium-based chiral, microporous, metal-organic framework compound [(CH3)2NH2][UO2(TPO)]•4DMF•12.5H2O (SCU-3) that exhibits the highest void volume (68.8%) and second-harmonic generation (SHG) efficiency (1.54 KDP) for an actinide compound reported to date. The combination of large channels and the coordination capabilities of P=O moieties in the structure enables SCU-3 to capture large amounts of Th(IV) from aqueous solutions, providing a new strategy for preparing heterobimetallic 5f/5f compounds, and may lead to applications in nuclear waste management.