报告题目:锕酰离子成键规律的理论研究

报告人:胡淑贤 副研究员 北京计算科学研究中心

报告时间:2019727日 上午930

报告地点:402号楼一楼会议室

              欢迎广大师生踊跃参加!

               欧洲杯官网

报告人简介:胡淑贤,2013年于中国科学院获理论化学博士学位。毕业后先后在日本早稻田大学和清华大学进行博士后研究工作。2016年任职北京计算科学研究中心副研究员。主要研究的领域与兴趣包括:重金属元素及 f 族元素(镧系和锕系)配合物的电子结构计算、化学成键分析及光谱模拟。

报告简介:To further fundamental understanding of the nature and extent of covalency in actinylligand bonding, and the benefits that this may have for the design of new ligands for nuclear waste separation, there is burgeoning interest in the nature of actinyl complexes with polydentate or multiple-point-donor ligands, such as crown ethers and porphyrin. There are few cases of structurally authenticated molecular actinylcrown bonds under ambient conditions. This talk will report the computational characterization of AnO22+L complexes, where An = U, Np, Pu, Am, and Cm, and L is the cyclic polyether ligand with five or six coordination atoms.