主题：Postsynthetic Exchange of Hybrid Inorganic-Organic Solids: From Intercalation Chemistry to Chemical Functionalization

报告人：费泓涵  同济大学高等研究院暨化学系特聘研究员，博士生导师

报告时间：2015年4月3日下午1:30

报告地点：欧洲杯官网会议室（医学楼401栋三楼会议室）

       欢迎广大师生踊跃参加！

                     医学部欧洲杯官网

                     放射医学及交叉学科研究院

报告摘要:  The first part of this presentation will describe our progress in using anionic structural directing agents to template high-dimensional cationic inorganic frameworks, which exhibited anion-based applications. The second part of this presentation will report our recent findings on postsynthetic ligand exchange of robust metal-organic frameworks (MOFs), and their heterogeneous catalysis chemistry.

报告人简介：费泓涵博士于2007年获复旦大学化学系理学学士学位，2012年7月在美国加州大学圣克鲁斯分校获博士学位, 师从材料化学家Scott R. J. Oliver教授，自2012至2015年在加州大学圣地亚哥分校化学系进行博士后，师从无机化学家Seth M. Cohen教授暨系主任，致力于金属有机框架结构的有机配体修饰及交换方面的研究。今年3月起任同济大学高等研究院暨化学系特聘研究员，博士生导师，主要从事无机层状晶格与金属有机框架材料的研究。近五年来在JACS、ACIE 、PNAS等国际化学和材料领域顶尖期刊上发表学术论文23篇，以第一作者身份发表17篇，论文他引500余次。2011和2012年连续2年获得国际衍射数据中心颁发的Ludo Frevel晶体学奖。

近五年代表性论文：

(1) Honghan Fei, Seth M. Cohen* “Metalation of a Thiocatechol-Functionalized Zr(IV)-based Metal-Organic Framework for Selective C-H Functionalization.” J. Am. Chem. Soc., 2015, 137, 2191-2194.

(2) Honghan Fei, JaeWook Shin, Ying S. Meng, Mario Adelhardt, Jorg Sutter, Karsten Meyer, Seth M. Cohen* “Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal-Organic Framework.” J. Am. Chem. Soc., 2014, 136, 4965-4973.

(3) Sonja Pullen?, Honghan Fei?, Andreas Orthaber, Seth M. Cohen*, Sascha Ott* “Enhanced Photochemical Hydrogen Production by a Molecular Diiron Catalyst Incorporated into a Metal-Organic Framework.” J. Am. Chem. Soc., 2013, 135, 16997-17003 (?equal contribution).

(4) Honghan Fei, Catherine H. Pham, Scott R. J. Oliver* “Anion Exchange of the Cationic Layered Material [Pb2F2]2+.” J. Am. Chem. Soc., 2012, 134, 10729-10732.

(5) Honghan Fei, Scott R. J. Oliver* “Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High-Capacity Anion Exchange.” Angew. Chem. Int. Ed., 2011, 123, 9232-9236.

(6) Honghan Fei, Marc R. Bresler, Scott R. J. Oliver* “A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials.” J. Am. Chem. Soc., 2011, 133, 11110-11113.

(7) Honghan Fei, David L. Rogow, Scott R. J. Oliver* “Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal-Organic Frameworks Based on Cu(I) and Ag(I)” J. Am. Chem. Soc., 2010, 132, 7202-7209.